Data di Pubblicazione:
2016
Abstract:
A series of carbons were prepared by pyrolysis of hyper cross-linked cyclodextrins, also known as nanosponges (NS). Pore structure analysis showed that pores with a range size of 5–16 A can be created from β-CD an NS cross-linked with pyromellitic dianhydride (PY). NS cross-linked with hexamethylene diisocyanate (HD) was ineffective to produce pores. SEM observation reveals a peculiar morphology of the PY-NS carbon, made of perfectly spherical hollow particles. TGA and FT-IR studies demonstrate that the PY-NS is the more efficient carbon precursor.
Tipologia CRIS:
03A-Articolo su Rivista
Keywords:
Carbon; Carbonization; Cyclodextrin; Hollow spheres; Hyper cross-linked cyclodextrins; Microporous carbon; Nanosponges; Pyrolysis; Chemistry (all); Materials Science (all); Condensed Matter Physics; Mechanics of Materials
Elenco autori:
Zanetti, Marco; Anceschi, Anastasia; Magnacca, Giuliana; Spezzati, Giulia; Caldera, Fabrizio; Rosi, Giovanni Paolo; Trotta, Francesco
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