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  1. Pubblicazioni

Nanosponge-Based Composite Gel Polymer Electrolyte for Safer Li-O2 Batteries

Articolo
Data di Pubblicazione:
2021
Abstract:
Li-O2 batteries represent a promising rechargeable battery candidate to answer the energy challenges our world is facing, thanks to their ultrahigh theoretical energy density. However, the poor cycling stability of the Li-O2 system and, overall, important safety issues due to the formation of Li dendrites, combined with the use of organic liquid electrolytes and O2 cross-over, inhibit their practical applications. As a solution to these various issues, we propose a composite gel polymer electrolyte consisting of a highly cross-linked polymer matrix, containing a dextrin-based nanosponge and activated with a liquid electrolyte. The polymer matrix, easily obtained by thermally activated one pot free radical polymerization in bulk, allows to limit dendrite nucleation and growth thanks to its cross-linked structure. At the same time, the nanosponge limits the O2 cross-over and avoids the formation of crystalline domains in the polymer matrix, which, combined with the liquid electrolyte, allows a good ionic conductivity at room temperature. Such a composite gel polymer electrolyte, tested in a cell containing Li metal as anode and a simple commercial gas diffusion layer, without any catalyst, as cathode demonstrates a full capacity of 5.05 mAh cm−2 as well as improved reversibility upon cycling, compared to a cell containing liquid electrolyte.
Tipologia CRIS:
03A-Articolo su Rivista
Keywords:
Li-O2 cell, composite gel polymer electrolyte, nanosponge, O2 cross-over
Elenco autori:
Amici, Julia; Torchio, Claudia; Versaci, Daniele; Dessantis, Davide; Marchisio, Andrea; Caldera, Fabrizio; Bella, Federico; Francia, Carlotta; Bodoardo, Silvia
Autori di Ateneo:
CALDERA Fabrizio
Link alla scheda completa:
https://iris.unito.it/handle/2318/1807164
Link al Full Text:
https://iris.unito.it/retrieve/handle/2318/1807164/820277/polymers-13-01625-v2%20(1).pdf
Pubblicato in:
POLYMERS
Journal
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URL

https://www.mdpi.com/2073-4360/13/10/1625/htm
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