Data di Pubblicazione:
1996
Abstract:
The role of the catalyst surface acid-base properties on the heterogeneously-catalyzed oxidation reaction mechanisms is discussed. Acid-base properties depend on the covalent/ionic character of the metal-oxygen bonds and are involved in some steps of the oxidation reactions, such as the activation of the C-H hydrocarbon bonds, the step associated with the evolution of alkoxide species and the desorption/overoxidation of the partial oxidation products. Thus they participate with the cation redox properties in determining the selective/unselective catalyst behavior.
Tipologia CRIS:
03A-Articolo su Rivista
Elenco autori:
G. Busca;E. Finocchio;G. Ramis;G. Ricchiardi
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