Data di Pubblicazione:
2015
Abstract:
The interaction of H2S with HKUST-1 and ZIF-8 MOFs has been studied by means of FT-IR, Raman, DRUVVis-NIR
and PXRD techniques. At very low equilibrium pressure (below 5 mbar) a stepwise structural
distortion is observed in both HKUST-1 and ZIF-8. At higher equilibrium pressures (20e60 mbar), PXRD
technique, in particular, showed the structural destruction of HKUST-1 with formation of a covallite (CuS)
phase and some structural distortion of ZIF-8.
Tipologia CRIS:
03A-Articolo su Rivista
Keywords:
Hydrogen sulfide, IR spectroscopy, Metal-organic frameworks, Raman spectroscopy, X-ray diffraction,
Elenco autori:
Ethiraj, Jayashree; Bonino, Francesca; Lamberti, Carlo; Bordiga, Silvia
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