Functionalizing the Defects: Postsynthetic Ligand Exchange in the Metal Organic Framework UiO-66
Articolo
Data di Pubblicazione:
2016
Abstract:
Herein, we explore the possibility of functionalizing UiO-66 with the monoethanolamine (MEA) moiety. Several unsuccessful routes are discussed before we show that it can be achieved via a 2 stage post synthetic ligand exchange (PSE) reaction with a highly defective UiO-66 sample. The intermediate material is the most porous UiO-66 sample ever reported. We expect that this novel approach will allow many other functional moieties to be introduced.
Tipologia CRIS:
03A-Articolo su Rivista
Keywords:
Metallorganic Framework UiO-66; Post synthetic functionalization; Modulator
Elenco autori:
Shearer, Greig C.; Vitillo, Jenny G.; Bordiga, Silvia; Svelle, Stian; Olsbye, Unni; Lillerud, Karl Petter
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